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Chiral analysis of pesticides and drugs of environmental concern: biodegradation and enantiomeric fraction

2017Journal article Open access
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dc.contributor.authorMaia, Alexandra S.
dc.contributor.authorRibeiro, Ana R.
dc.contributor.authorCastro, Paula M. L.
dc.contributor.authorTiritan, Maria Elizabeth
dc.date.accessioned2017-12-18T19:45:35Z
dc.date.available2017-12-18T19:45:35Z
dc.date.issued2017
dc.description.abstractThe importance of stereochemistry for medicinal chemistry and pharmacology is well recognized and the dissimilar behavior of enantiomers is fully documented. Regarding the environment, the significance is equivalent since enantiomers of chiral organic pollutants can also differ in biodegradation processes and fate, as well as in ecotoxicity. This review comprises designed biodegradation studies of several chiral drugs and pesticides followed by enantioselective analytical methodologies to accurately measure the enantiomeric fraction (EF). The enantioselective monitoring of microcosms and laboratory-scale experiments with different environmental matrices is herein reported. Thus, this review focuses on the importance of evaluating the EF variation during biodegradation studies of chiral pharmaceuticals, drugs of abuse, and agrochemicals and has implications for the understanding of the environmental fate of chiral pollutants.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationMaia, A. S., Ribeiro, A. R., Castro, P. M. L., & Tiritan, M. E. (2017). Chiral analysis of pesticides and drugs of environmental concern: Biodegradation and enantiomeric fraction. Symmetry-Basel, 9(9), 196pt_PT
dc.identifier.doi10.3390/sym9090196pt_PT
dc.identifier.eid85031428199
dc.identifier.issn2073-8994
dc.identifier.urihttp://hdl.handle.net/10400.14/23730
dc.identifier.wos000411526000029
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherMDPI
dc.relationFCOMP-01-0124-FEDER-022718pt_PT
dc.relationFLUOROPHARMA - Biodegradation and removal of chiral and achiral fluorinated pharmaceuticals from wastewaters
dc.relationStrategic Project - LA 16 - 2011-2012
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectEnantiomeric fraction (EF)pt_PT
dc.subjectEnantioselectivitypt_PT
dc.subjectChiral analysispt_PT
dc.subjectBiodegradationpt_PT
dc.subjectPesticidespt_PT
dc.subjectPharmaceuticalspt_PT
dc.titleChiral analysis of pesticides and drugs of environmental concern: biodegradation and enantiomeric fractionpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleFLUOROPHARMA - Biodegradation and removal of chiral and achiral fluorinated pharmaceuticals from wastewaters
oaire.awardTitleStrategic Project - LA 16 - 2011-2012
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FEBB-EBI%2F111699%2F2009/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F86939%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/PEst-OE%2FEQB%2FLA0016%2F2011/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/PEst-OE%2FSAU%2FUI4040%2F2014/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FMulti%2F04423%2F2013/PT
oaire.citation.issue9pt_PT
oaire.citation.titleSymmetrypt_PT
oaire.citation.volume9pt_PT
oaire.fundingStream3599-PPCDT
oaire.fundingStreamSFRH
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream5876
oaire.fundingStream5876
person.familyNameMaia
person.familyNameRibeiro
person.familyNameCastro
person.familyNameTiritan
person.givenNameAlexandra S.
person.givenNameAna Rita Lado
person.givenNamePaula
person.givenNameMaria Elizabeth
person.identifier903786
person.identifier2013444
person.identifier1310409
person.identifier.ciencia-id6A15-F0A3-AEF2
person.identifier.ciencia-id421D-DC6E-F6E3
person.identifier.ciencia-id7C1F-6C72-354A
person.identifier.ciencia-idD915-BFC0-FB3A
person.identifier.orcid0000-0002-4167-383X
person.identifier.orcid0000-0002-4445-5379
person.identifier.orcid0000-0001-8841-6606
person.identifier.orcid0000-0003-3320-730X
person.identifier.ridM-8241-2013
person.identifier.ridK-9492-2014
person.identifier.scopus-author-id55332349300
person.identifier.scopus-author-id57207918943
person.identifier.scopus-author-id7102781782
person.identifier.scopus-author-id6602890981
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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