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Rheological study into the ageing process of high methoxyl pectin/sucrose aqueous gels

dc.contributor.authorSilva, J. A. Lopes da
dc.contributor.authorGonçalves, M. P.
dc.date.accessioned2011-09-13T13:52:31Z
dc.date.available2011-09-13T13:52:31Z
dc.date.issued1994
dc.description.abstractThe ageing process of high methoxyl pectin (HMP)/sucrose gels was followed at different ageing temperatures by small amplitude oscillatory experiments. Dynamic mechanical measurements allowed the characterisation of the point at which the system undergoes the sol/gel transition. The HMP/sucrose system is extremely sensitive to temperature variation during ageing, especially in the lower temperature range. The viscoelastic behaviour through the gel point changes with the ageing temperature, probably due to variations in mobility of the pectin chains, and consequently, in the lifetime of junction zones. Weaker pectin networks are formed under thermal conditions unfavourable to the development of hydrophobic interactions. Gel time and elastic modulus have a complex dependence on temperature, which could be attributed to the different thermal behaviour of the intermolecular interactions that stabilise the nonpermanent cross links of these physical networks.por
dc.identifier.citationSILVA, J. A. Lopes da ; GONÇALVES, M. P. - Rheological study into the ageing process of high methoxyl pectin/sucrose aqueous gels. Carbohydrate Polymers. ISSN 0144-8617. Vol. 24, n.º 4 (1994), p. 235-245por
dc.identifier.doi10.1016/0144-8617(94)90068-X
dc.identifier.eid0028745993
dc.identifier.urihttp://hdl.handle.net/10400.14/5470
dc.identifier.wosA1994PP11700001
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.titleRheological study into the ageing process of high methoxyl pectin/sucrose aqueous gelspor
dc.typejournal article
dspace.entity.typePublication
person.familyNameSilva
person.givenNameJoana
person.identifier.ciencia-idB415-743D-D9F9
person.identifier.orcid0000-0003-3977-7418
person.identifier.scopus-author-id7403023130
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication42069f79-2050-47f2-a42b-fab5c301e9a3
relation.isAuthorOfPublication.latestForDiscovery42069f79-2050-47f2-a42b-fab5c301e9a3

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