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Chemical composition of red, brown and green macroalgae from Buarcos bay in Central West Coast of Portugal

Publication . Rodrigues, Dina; Freitas, Ana C.; Pereira, Leonel; Rocha-Santos, Teresa A. P.; Vasconcelos, Marta W.; Roriz, Mariana; Rodríguez-Alcalá, Luís M.; Gomes, Ana M. P.; Duarte, Armando C.

Six representative edible seaweeds from the Central West Portuguese Coast, including the less studied Osmundea pinnatifida, were harvested from Buarcos bay, Portugal and their chemical characterization determined. Protein content, total sugar and fat contents ranged between 14.4% and 23.8%, 32.4% and 49.3% and 0.6–3.6%. Highest total phenolic content was observed in Codium tomentosum followed by Sargassum muticum and O. pinnatifida. Fatty acid (FA) composition covered the branched chain C13ai to C22:5 n3 with variable content in n6 and n3 FA; low n6:n3 ratios were observed in O. pinnatifida, Grateloupia turuturu and C. tomentosum. Some seaweed species may be seen as good sources of Ca, K, Mg and Fe, corroborating their good nutritional value. According to FTIR-ATR spectra, G. turuturu was associated with carrageenan seaweed producers whereas Gracilaria gracilis and O. pinnatifida were mostly agar producers. In the brown algae, S. muticum and Saccorhiza polyschides, alginates and fucoidans were the main polysaccharides found.

2015Journal article

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Disposable sensors for environmental monitoring of lead, cadmium and mercury

Publication . Duarte, Katia; Justino, Celine I. L.; Freitas, Ana C.; Gomes, Ana M. P.; Duarte, Armando; Rocha-Santos, Teresa A. P.

Miniaturization is an increasing trend in the field of analytical chemistry as a response to the need to develop new analytical techniques for food, clinical, and environmental applications. There is therefore also an increasing trend towards the use of miniaturized disposable sensors, which are inexpensive and designed to be one-shot and do not require pre-treatment prior to use or cleaning between measurements. This review describes disposable sensors for detection of lead, cadmium and mercury in the environment, taking into account their analytical performance. Further, we also discuss the role of certain factors, such as the immobilization procedure and surface modification affecting the analytical characteristics of sensors. Finally, we comment on future applications and potential research interest in this field.

2015Journal article

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