Publicação
The effect of porosity on the catalytic performance of constant-mass, spherical beads containing immobilized enzyme
| dc.contributor.author | Cruz, I. B. | |
| dc.contributor.author | Malcata, F. X. | |
| dc.date.accessioned | 2011-10-21T16:47:53Z | |
| dc.date.available | 2011-10-21T16:47:53Z | |
| dc.date.issued | 1998 | |
| dc.description.abstract | The mass balances to a spherical bead with increasing porosity, e (obtained by plain expansion of an otherwise compact bead), containing an immobilized enzyme and surrounded by a stagnant ®lm are developed in dimensionless form for the case of Michaelis-Menten kinetics by considering three alternative situations in terms of pore structure (either setting the pore number, the pore radius or the pore length as a constant). The pore pattern of the porous bead does not play a major role in the variation of the lowest concentration of substrate ever reached in the bulk of the bead, which increases as e increases and eventually levels off when e approaches unity. The ratio between the rate of reaction brought about by the immobilized enzyme within the porous bead and that obtained for a compact bead is greater when e is higher, and a vertical asymptote is apparently reached when the porosity approaches unity, a trend that is similarly observed for all pore patterns considered. | por |
| dc.identifier.citation | CRUZ, I. B.; MALCATA, F. X. - The effect of porosity on the catalytic performance of constant-mass, spherical beads containing immobilized enzyme. Bioprocess Engineering. ISSN 0178-515X. Vol. 19 (1998), p.269-275 | por |
| dc.identifier.uri | http://hdl.handle.net/10400.14/6751 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Springer-Verlag | por |
| dc.title | The effect of porosity on the catalytic performance of constant-mass, spherical beads containing immobilized enzyme | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| person.familyName | Malcata | |
| person.givenName | Francisco | |
| person.identifier.ciencia-id | 1B13-38A5-35F5 | |
| person.identifier.orcid | 0000-0003-3073-1659 | |
| person.identifier.scopus-author-id | 7102542478 | |
| rcaap.rights | restrictedAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | a06c00da-0e2f-4434-8ede-4d7b22c0dfe9 | |
| relation.isAuthorOfPublication.latestForDiscovery | a06c00da-0e2f-4434-8ede-4d7b22c0dfe9 |
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