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Hydroxyapatite and chloroapatite derived from sardine by-products

2014Journal article Restricted access
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dc.contributor.authorPiccirillo, C.
dc.contributor.authorPullar, R. C.
dc.contributor.authorTobaldi, D. M.
dc.contributor.authorCastro, Paula M. L.
dc.contributor.authorPintado, M. E.
dc.date.accessioned2015-05-12T14:59:49Z
dc.date.available2015-05-12T14:59:49Z
dc.date.issued2014
dc.description.abstractIn this paper, phosphate-based compounds used in biomedicine were extracted from bones and scales of European sardines (Sardina pilchardus); this is the first time that different parts of the same fish are used for the extraction of these kinds of materials. The bones and scales behave very differently with processing, producing different materials when annealed between 600 and 1000 °C. The bones formed a mixture of hydroxyapatite (Ca10(PO4)6(OH)2, HAp) and β-tri-calcium phosphate (β-Ca3(PO4)2, β-TCP), with a higher content of β-TCP obtained with increasing temperature. This bi-phasic material has a high added value, as it is employed as a bioceramic; in fact HAp has good biocompatibility while β-TCP has better resorbability than HAp, despite being less biocompatible. With scales, on the other hand, either a HAp-based material or a chlorine-substitute HAp containing material (chloroapatite (Ca10(PO4)6Cl2, ClAp) were produced. HAp-based material was obtained with a simple annealing process; for ClAp, on the other hand, a combined washing–annealing process was used. ClAp is also used in biomedicine, due to its improved resorption, mechanical properties and bioactivity. This is the first time ClAp of marine origin was produced.por
dc.description.versioninfo:eu-repo/semantics/publishedVersion
dc.identifier.citationPICCIRILLO, C… [et al.] - Hydroxyapatite and chloroapatite derived from sardine by-products. Ceramics International, 40 (8 PART B) (2014), p. 13231-13240por
dc.identifier.doi10.1016/j.ceramint.2014.05.030
dc.identifier.issn0272-8842
dc.identifier.urihttp://hdl.handle.net/10400.14/17571
dc.identifier.wosWOS:000340321300079
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevier
dc.subjectBone implantspor
dc.subjectBones and scales fish by-productspor
dc.subjectCalcium phosphatepor
dc.subjectChloroapatitepor
dc.subjectHydroxyapatitepor
dc.titleHydroxyapatite and chloroapatite derived from sardine by-productspor
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F86483%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/COMPETE/PEst-C%2FCTM%2FLA0011%2F2013/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PEst-OE%2FEQB%2FLA0016%2F2013/PT
oaire.citation.endPage13240
oaire.citation.issue8
oaire.citation.startPage13231
oaire.citation.titleCeramics International
oaire.citation.volume40
oaire.fundingStreamSFRH
oaire.fundingStreamCOMPETE
oaire.fundingStream3599-PPCDT
person.familyNamePiccirillo
person.familyNamePullar
person.familyNameTobaldi
person.familyNameCastro
person.familyNamePintado
person.givenNameClara
person.givenNameRobert
person.givenNameDavid Maria
person.givenNamePaula
person.givenNameMaria Manuela
person.identifier962551
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person.identifier.orcid0000-0002-0112-8570
person.identifier.orcid0000-0001-8841-6606
person.identifier.orcid0000-0002-0760-3184
person.identifier.ridN-8206-2013
person.identifier.ridM-8241-2013
person.identifier.ridF-5696-2013
person.identifier.scopus-author-id7004621626
person.identifier.scopus-author-id7003296532
person.identifier.scopus-author-id16319626100
person.identifier.scopus-author-id7102781782
person.identifier.scopus-author-id7004483898
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
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