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Nor-isoprenoids profile during port wine ageing—influence of some technological parameters

dc.contributor.authorFerreira, António César Silva
dc.contributor.authorPinho, Paula Guedes de
dc.date.accessioned2010-11-19T13:26:40Z
dc.date.available2010-11-19T13:26:40Z
dc.date.issued2004
dc.description.abstractNor-isoprenoid compounds, such as β-damascenone, β-ionone, 2,2,6-trimethylcyclohexanone (TCH), 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) and vitispirane were determined in 14 young port wines and 45 old port wines. As between the two groups of wines levels of these compounds are quite different, an experimental protocol was performed in order to determine which technological parameter (dissolved O2, free SO2 levels, pH and time/temperature) was related with the formation/consumption of these molecules. The five nor-isoprenoids were equally affected by the selected parameters and a similar profile with time was observed. The synergistic effects of increasing temperature and lowering pH had the largest impact. For samples treated with high oxygen regimes (saturation), the levels of all considered nor-isoprenoids decreased after a certain concentration of oxygen consumed (e.g. 10 mg l−1). Nevertheless, during barrel port wine ageing, corresponding to the 45 wines, two different behaviours can be observed: TDN, vitispirane and TCH increase significantly whilst a decrease of levels of β-ionone and β-damascenone with port barrel ageing was observed. It was also calculated that “over 40 year” old port wines have, respectively, 15, 5 and 3 times higher levels of TDN, vitispirane and TCH than the young ports. For these three compounds the respective rates of formation are higher than those of degradation, which suggests a higher number or higher concentration of precursors than those involved for the megastigame C13 nor-isoprenoids β-damascenone and β-ionone.por
dc.identifier.citationFERREIRA, António César Silva ; PINHO, Paula Guedes de - Nor-isoprenoids profile during port wine ageing—influence of some technological parameters. Analytica Chimica Acta. ISSN 0003-2670. Vol. 513, n.º 1 (2004), p. 169-176por
dc.identifier.doi10.1016/j.aca.2003.12.027
dc.identifier.urihttp://hdl.handle.net/10400.14/3520
dc.language.isoengpor
dc.publisherElsevierpor
dc.subjectPort winespor
dc.subjectAgeingpor
dc.subjectVolatile nor-isoprenoid compoundspor
dc.subjectβ-Damascenonepor
dc.subjectβ-Iononepor
dc.subject2,2,6-trimethylcyclohexanonepor
dc.subject1,1,6-trimethyl-1,2-dihydronaphthalenepor
dc.subjectVitispiranepor
dc.titleNor-isoprenoids profile during port wine ageing—influence of some technological parameterspor
dc.typejournal article
dspace.entity.typePublication
person.familyNameSilva Ferreira
person.familyNameGuedes de Pinho
person.givenNameAntonio Cesar
person.givenNamePaula
person.identifier392870
person.identifier.ciencia-id931A-48DA-23A8
person.identifier.ciencia-id2510-1418-EF48
person.identifier.orcid0000-0002-1188-1021
person.identifier.orcid0000-0002-7395-5700
person.identifier.scopus-author-id6504448214
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication826c11dd-d070-4b67-ac58-c96675e3f3b8
relation.isAuthorOfPublication0bde318f-79f7-4130-8600-e553f3384cc6
relation.isAuthorOfPublication.latestForDiscovery826c11dd-d070-4b67-ac58-c96675e3f3b8

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